A High-Sensitive Polarography in Highly Viscous Supporting Electrolyte Solution Using Stationary Mercury Electrode
نویسندگان
چکیده
منابع مشابه
ELECTROCHEMICAL BEHAVIOUR OF U(V1) NITRATE IN CHLOROFORM AT A MERCURY ELECTRODE THE DEPENDENCE ON SUPPORTING ELECTROLYTE
The mechanistic aspects of the electrochemical reduction of U(V1) nitrate at a mercury electrode in chloroform, using three different supporting electrolytes, are described. In the presence of tetrabutylarnmonium perchlorate (TBAP) as a neutral electrolyte, UO (NO ) , reduced in two irreversible electrochemical steps to form a U(V1)-U(V) binuclear complex and U(IV), respectively. In the pr...
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متن کاملelectrochemical behaviour of u(v1) nitrate in chloroform at a mercury electrode the dependence on supporting electrolyte
the mechanistic aspects of the electrochemical reduction of u(v1) nitrate at a mercury electrode in chloroform, using three different supporting electrolytes, are described. in the presence of tetrabutylarnmonium perchlorate (tbap) as a neutral electrolyte, uo (no ) , reduced in two irreversible electrochemical steps to form a u(v1)-u(v) binuclear complex and u(iv), respectively. in the presenc...
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A highly sensitive differential pulse polarographic method has been developed for the estimation of tegaserod maleate after treating it with hydrogen peroxide solution. The oxidation of tegaserod maleate is a reversible process as the oxidized product could be reduced at hanging mercury drop electrode in a quantitative manner using differential pulse polarography mode. The limit of quantificati...
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ژورنال
عنوان ژورنال: Review of Polarography
سال: 1962
ISSN: 0034-6691,1884-7692
DOI: 10.5189/revpolarography.10.33